For a table bc_roads in the bc schema with a geometry column the_geom...
To get the extent as a Well-known text (WKT) box:
SELECT Extent(the_geom) AS extent FROM bc.bc_roads;
To get the extent as xmax, xmin, ymax, ymin as fields:
SELECT ST_XMax(r) AS xmax, ST_XMin(r) AS xmin, ST_YMax(r) AS ymax, ST_YMin(r) AS ymin FROM (SELECT ST_Collect(the_geom) AS r FROM bc.bc_roads) AS foo;